Collection and identification of gases

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C7.07 Methods for collecting gases
downward delivery
suitable for heavy dense gas solubility not important e.g. chlorine, 

upward delivery
suitable for light low density gas, solubility not important e.g hydrogen

collection over water
Suitable for any gas with a low solubility e.g. nitrogen

collection using a gas syringe
Suitable for any gas especially if volume is to be measured.

Learning activity - use the data in the table and the rules above to select a collection method and give a reason.

gas relative density water solubility method reason
air 14.4 low X X
oxygen 16 low    
hydrogen 1 low    
carbon dioxide 22 low    
nitrogen 14 very low    
ammonia 8.5 very high    
methane 8 low    
chlorine 35.5 high    
sulfur dioxide 32 high    
helium 2 very low    

C7.08 Testing for common gases

Gas test positive result
hydrogen light with burning splint squeaky pop
oxygen test with glowing splint splint relights
ammonia damp red litmus
smell
turns blue
pungent
hydrogen chloride damp blue litmus
open ammonia bottle
smell
turns red
white smoke above bottle
sharp
carbon dioxide bubble through limewater limewater turns milky
sulfur dioxide damp blue litmus
damp dichromate paper
smell
turns red
turns from orange to green
sharp

C7.09 Hazards with common gases
Hydrogen - flammable,  explosive when mixed with air. Use in small amounts.
Hydrogen chloride and sulphur dioxide- poisonous as they are very acidic.  Use small amounts and only in the fume cupboard.