Transition metal sulfur containing organic compounds are versatile materials, which are used as high-temperature lubricants, hydrogenation catalysts and high-energy density batteries.
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We are interested in developing new routes to transition metal sulfides via chemical vapour deposition and sol-gel processes. Therefore we are developing some transition metal thiolates [M(SR)n ] (Figure 1). |

Figure 1. View of the
structure of [Nb(SC6H3Me2-2,6)5 ].
Adapted from http://www.chem.ucl.ac.uk/people/carmalt/index.html